Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids.

نویسندگان

  • Sam Bullock
  • Andrew J Hallett
  • Lindsay P Harding
  • Joshua J Higginson
  • Sean A F Piela
  • Simon J A Pope
  • Craig R Rice
چکیده

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)(3)Cl complex of 3,3'-diamino-2,2'-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 48  شماره 

صفحات  -

تاریخ انتشار 2012